Forum Replies Created

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  • chemicalmatt

    Member
    November 14, 2018 at 10:11 pm in reply to: Salicylic acid 20 %solution

    IF you can live with some little benzyl alcohol or phenoxyethanol in your formula, those two will increase SalAc solubility and are miscible with PG too. 

  • chemicalmatt

    Member
    November 14, 2018 at 10:05 pm in reply to: Isopentyldiol and Propanediol

    TO reduce “sticky”, or tack, just use butylene glycol. Cheap, safe, more effective than those two diols you mentioned. Also, BG is no more or less moisturizing than the two you mentioned, meaning very little.

  • chemicalmatt

    Member
    November 8, 2018 at 8:45 pm in reply to: Pressing cosmetics

    Hard to say Tal without more ingredient info. Minerals? Carriers? Waxes?

  • chemicalmatt

    Member
    November 8, 2018 at 8:42 pm in reply to: Can glucosides really work as emulsifiers?

    My experience, you always need a co-emulsifier with those. They will work, just not alone. Olive oil is quite the polar triglyceride, as CriticalM mentioned, BTW.

  • chemicalmatt

    Member
    November 8, 2018 at 8:40 pm in reply to: Brainstorming: What are your favorite fragrance emulsifiers?

    PolySugaMulse D-9 hands down the best. Use ratio ~3:1but as everyone here said: all depends on what. Cyclomethicone? Yeesh! 

  • chemicalmatt

    Member
    October 25, 2018 at 7:34 pm in reply to: Please improve my hair conditioner lotion recipe

    nicotero, ignore all of the above.  Just decrease cetyl alcohol and the viscosity will decrease with it. See: liquid crystal formation with fatty alcohols. 

  • chemicalmatt

    Member
    October 25, 2018 at 7:29 pm in reply to: A new chemical finder website comes online

    Cool, Perry. You have our collective thanks. I’ll add one of my faves here, ‘cuz why not? Liberty Natural Products [www.libertynatural.com] for essential oils at really good prices, low MOQ.

  • chemicalmatt

    Member
    October 25, 2018 at 7:20 pm in reply to: Hair Mask with gumlike / slimy texture

    Chris, I would not expect a haircare product with that ingredient base to be slimy at all, so your results are not surprising. There is another additive in that product that is not listed (Pectin maybe?) Perhaps your client can live with something that may be, in my opinion, better, such as what you obtained? Who needs gummy anyway? An aside: whomever formulated that mask sure liked Croda.

  • chemicalmatt

    Member
    October 25, 2018 at 7:01 pm in reply to: On Ascorbates

    I may be wrong, but isn’t the function of vitamin C (derivatives) to act as a collagen reductase inhibitor in the SC? I have not worked with it as much as Mark, so I can’t weigh in on the differences; I thought defining the mechanism of action could point you in the right research direction.

  • chemicalmatt

    Member
    October 21, 2018 at 10:23 pm in reply to: Difference between EDTA

    Should make little difference in your formulation as long as you aren’t using an electrolyte-sensitive rheology agent - like Carbopol, for instance. That’s why the disodium EDTA is so common.

  • This would require a seminar to answer effectively.

  • chemicalmatt

    Member
    October 21, 2018 at 10:18 pm in reply to: sos change of color

    Somewhat weird. Using only iron oxides?

  • chemicalmatt

    Member
    October 21, 2018 at 10:16 pm in reply to: Adding Dimethicone to Lip Balm?

    Try it and see. Dimethicone is not miscible with any of those ingredients but could be coupled with an ester. 

  • chemicalmatt

    Member
    October 17, 2018 at 4:54 pm in reply to: Help Needed From Experts in Hair Science

    No such book exists that I know of, gabby, and I’ve been formulating multi-cultural hair-care products for a LOT of years. Look into some specialty chemical sites, such as Croda, Inolex, Evonik, even BASF(!), RITA, just to name a few. Many of these manufacturers have developed formularies for “ethnic” hair-care (archaic term) over the years. Also Michelle Breyers website [www.naturallycurly.com] has cues.  Good luck.  

  • chemicalmatt

    Member
    October 17, 2018 at 4:48 pm in reply to: On extracts and how effective they are

    I would not label hyaluronic acid “an extract.” Just sayin’

  • chemicalmatt

    Member
    October 17, 2018 at 4:46 pm in reply to: surfactants and emulsifiers

    20% NaCl in a o/w emulsion? Stable? Low viscosity? Sprayable? - good luck with that.

  • chemicalmatt

    Member
    October 17, 2018 at 4:44 pm in reply to: Clay mask pH

    Metal ion hydrolysis at work. Try using a buffer.

  • chemicalmatt

    Member
    October 17, 2018 at 4:42 pm in reply to: Difference between EDTA

    This is a chemistry question ZivBA.  Look into Formation Constants for multivalent metal ions with various sequestrants. Then there are Chelation Values to be researched for these sequestrants. These differ for each ion at different pH ranges.  The “tri” sodium EDTA is less effective than “di” for most common ions when the pH is lower than 8.0.  Generally, “Tetra” works best for all formulations above pH 7.0.

  • chemicalmatt

    Member
    October 12, 2018 at 1:57 pm in reply to: Emulsifiers for O/W Emulsions (Body Lotions)

    What the “high level” you are seeking to emulsify would be the relevant information here. As Perry informs, the polar nature of your oil load would dictate the chemical composition of your emulsifiers, based on the tried & true HLB system. However, as ngarayeva infers, should you have a really high level, then use a polymeric emulsifier such as Pemulen TR-2. That can accommodate up to 40% w/w as long as your formula has no electrolytes. As always mentioned here, put in the lab time and experiment.

  • chemicalmatt

    Member
    October 11, 2018 at 8:24 pm in reply to: Sulfate-free Shampoo

    Widget: drop the polysorbate 20 and add more amphoteric (CAPB works OK, though not the best) and that will allow better dilution-deposition of the polyquat-10 onto hair, and you will feel better. Gunther was right: that is a lot of cationic polymer to use, depending on what MW it is. 

  • chemicalmatt

    Member
    October 11, 2018 at 8:15 pm in reply to: White refined beeswax has a smokey odor

    Strahl & Pitsch carries the best.

  • chemicalmatt

    Member
    October 11, 2018 at 8:12 pm in reply to: Cannibidiol label claims

    I did not inquire about the legal status of CBD, guys, nor its efficacy attributes; those I know well - and yes it is still Schedule 1 status as of today. I am interested in knowing the market label logic and presumptions about dosing that it implies. Mark, you partially answered, so thanks. Your client no doubt has to decide what mass “metered dose” is. From what I gleaned, and unless another party weighs in here, these label claims are just bull$&!#. I can put 0.01% w/w into a 60g jar and advise a client to  label it “200mg CBD”, even though it only contains 6. Who’s to know and who’s to care? It becomes a morality question only.

  • chemicalmatt

    Member
    October 11, 2018 at 2:45 pm in reply to: Penetrating into the hair

    For hydrophiles such as carboxylol cysteine, you may consider ethoxydiglycol (glycol ether DE). It is cheap too. For lipophilic components, dimethyl isosorbide works very well as a penetration enhancer. Still don’t know why it remains so expensive after all these years either.

  • chemicalmatt

    Member
    October 11, 2018 at 2:42 pm in reply to: Preservative in a salve

    Mark, isn’t d-Limonene the factor in that NLP-1 concoction? 

  • chemicalmatt

    Member
    October 11, 2018 at 2:31 pm in reply to: Oil and Ester Content of O/W Lotions

    Depends on what tactile effect you are looking for, Spadirect, and what oil/ester combo you are working with. Your’s is a VERY broad question!

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