Home Cosmetic Science Talk Formulating Changing a liquid soap into a shampoo?

  • Changing a liquid soap into a shampoo?

    Posted by Margaret2 on February 8, 2015 at 4:17 am

    I have a liquid soap which was made of  73% coconut oil & 27% olive oil. The final diluted soap  is preserved with suttocide A preservative at 0.5%, and scented with a bunch of citrus “essential oils” mixed with equal mass of polysorbate 20. 

     It makes LOTS of foam, but is thin. No big deal, we still wash our hair with it. The pH is around 8.5.  We  have not noticed it drying our hair or causing any negative effects.

    Would it be possible to mix it with ANY of the following surfactants to get a shampoo that will be thicker & with a lower pH? 
    If the answer is “Yep”, what % of the above-mentioned liquid soap & surfactant(s)  would you recommend for the final mix?
    We tend to have oily scalps, if you wish to know :(
    Here are the surfactants I can purchase for the potential mix:
    Cocamidopropyl Betaine
    Cocamide DEA
    Sodium C14-16 Olefin Sulfate
    Sodium Laureth Sulfate
    Caprylyl/Capryl Glucoside
    Decyl Glucoside 
    braveheart replied 9 years, 2 months ago 5 Members · 11 Replies
  • 11 Replies
  • belassi

    Member
    February 8, 2015 at 2:29 pm

    MEA seems to be compatible with CP soap so I would surmise that DEA is also likely to be (the pH is about right). I don’t see the point though of using natural soap, it is nowhere near as suitable as a synthetic shampoo.

  • OldPerry

    Member
    February 8, 2015 at 2:53 pm

    Yeah, I would suggest using the liquid soap for hand washing and just start from scratch for a shampoo.  You can make a nice one out of SLES / Betaine or create a more mild one with Decyl Glycoside.

  • Anonymous

    Guest
    February 8, 2015 at 3:51 pm

    Am I the only one who is confused with a whatever soap containing 100% (73%+27%) oils and producing foam? And pH can only be referred to a hydrophilic (water soluble) system as far as my knowledge.

  • Margaret2

    Member
    February 8, 2015 at 6:41 pm

    TO DISPEL THE CONFUSION: 

      It’s a liquid soap made from  the saponification between potassium hydroxide  &  coconut & olive oils. Potassium hydroxide is used to make liquid soaps. It foams REALLY well, like coconut oil-based soaps usually do. However, I learned that people with dry hair, either because of coloring or aging, etc. should NOT use soap made with a lot of coconut oil. 

     A commercial example of liquid soap is crazy Dr. Bonner’s peppermint soap. Have you ever tried to read the label??? CRAZY! 

         I was hoping I could use this liquid soap as the diluent with non-soap surfactants.  
    I certainly won’t argue that synthetic shampoos are better than liquid soap, but this soap does a good enough job for us. It’s just that the pH is 8.5 that has me a little concerned. Neither of us have straw-like hair from using it though. 
    Thanks for the  info. 
  • belassi

    Member
    February 8, 2015 at 7:15 pm

    Perhaps you are lucky enough to live in an area where the water is very soft. Liquid soap is terrible in a hard water area because it will leave your hair with Ca and Mg salts stuck to it.

  • belassi

    Member
    February 8, 2015 at 7:22 pm

    A commercial example of liquid soap is crazy Dr. Bonner’s peppermint soap. Have you ever tried to read the label??? CRAZY! 

    LOI from their Web site: Water, Organic Coconut Oil, Potassium Hydroxide, Organic Olive Oil, Mentha Arvensis, Organic Hemp Oil, Organic Jojoba Oil, Organic Peppermint Oil, Citric Acid, Tocopherol.

    - Quite simple actually because some of these things are just eye candy. I’d say the “Mentha Arvensis” is an essential oil and therefore <1% which means that the hemp and jojoba oils are only there for label appeal.
  • OldPerry

    Member
    February 8, 2015 at 10:08 pm

    They also don’t follow proper labeling rules.  Putting the term “organic” in an ingredient list is not correct.

  • Bobzchemist

    Member
    February 9, 2015 at 4:04 am

    It’s an inter-agency conflict, unfortunately. Putting “Organic” in the ingredient label is mandatory according to the USDA regulations for certified organic products, but it’s not correct according to the FDA’s regulations for cosmetic products. Most natural companies follow the USDA rules, because the consequences are more severe for not doing so.

  • OldPerry

    Member
    February 9, 2015 at 1:21 pm

    Shouldn’t they list their organic ingredients outside the LOI then include a proper LOI?

  • Bobzchemist

    Member
    February 10, 2015 at 3:08 am

    According to the FDA, yes. 

    But if they do, the USDA will yank the certification, and require them to immediately take all of the “organic”, “certified organic” and even “contains organic ingredients” off of the product label and all promotional materials.
    Ont the other hand, the FDA might make you pay a fine. Which would you rather risk?
  • braveheart

    Member
    February 12, 2015 at 6:35 pm

    Btw, did you test the pH of that liquid soap? It is usally quite alkali; I know because that was where I started my soap-making process and it will irritate acne-prone skin.

    I added seabuckthorn berry oil to my saponified soap and because of the irritation it can cause, I added citric acid and Cocodamipropyl betaine with lots of dilution, couldn’t be bothered with exactness (%) of the process and then xanthan gum. It gave me a balanced pH, but I won’t make liquid soap again.

    My suggestion, take Perry’s advice, start from scratch with your new ingredients.

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