

Bill_Toge
Forum Replies Created
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Bill_Toge
Professional Chemist / FormulatorMarch 24, 2021 at 7:31 pm in reply to: Shampoo color change and getting thin problem.the level of polyquaternium-7 (a cationic in a mostly anionic system) seems high, try reducing italso, what’s the purpose of the dipropylene glycol? glycols, particularly longer-chain ones, thin surfactant systems -
Bill_Toge
Professional Chemist / FormulatorMarch 24, 2021 at 7:18 pm in reply to: Shampoo vs bodywashsimilarly, I used to work for a white-label manufacturer, and the only significant difference was that they used slightly more expensive surfactants in a shampoo than they did in a bodywashcolour and fragrance aside, bodywash, shower gel, handwash and bath foam were all very similar variations on the same formula, the only difference being viscosity -
Bill_Toge
Professional Chemist / FormulatorMarch 20, 2021 at 9:27 pm in reply to: Anhydrous Sugar Scrub (question regarding heat stability)hydrogenated castor oil / castor wax (m.p. 70-80 °C / 158-176 °F) acts as a gelling agent and generally improves the thermal stability of oil-based products
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Bill_Toge
Professional Chemist / FormulatorMarch 12, 2021 at 8:07 pm in reply to: Xanthan gum vs Carbomerxanthan gum gives you a non-fluid ‘gel’ effect but with much longer flow than carbomer, and very little viscositya more comparable substitute for carbomer is gellan gum with sodium salts; this gives a strongly shear-thinning gel with short flow, similar to a carbomer -
Bill_Toge
Professional Chemist / FormulatorMarch 12, 2021 at 8:02 pm in reply to: Xylitol in Natural Toothpastefor what it’s worth, the major manufacturer of arginine is Ajinomoto (who also make 30% of the world’s supply of monosodium glutamate, and numerous other amino acid-related chemicals); if you can find a local distributor for their products, that’d be the most reliable source@Pharma arginine isn’t that strong a base compared to guanidine or hydroxide -
Carbomer 940 is much of a muchness between different manufacturers; I suspect that whether they know it or not, your customer is using a more electrolyte-tolerant grade of carbomer (electrolytes are what cause it to thin when it touches the skin)
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Bill_Toge
Professional Chemist / FormulatorMarch 9, 2021 at 12:07 am in reply to: Blue to Clear Liquid FormulationsI suspect the adhesive polymer (which matches INCI name with Daitosol 4000SJT) shows some slight fluorescence in solution, and the effect decreases as the product dries and the water evaporatesnot having seen the product or the polymer in question, this is pure speculation -
Bill_Toge
Professional Chemist / FormulatorMarch 4, 2021 at 11:24 pm in reply to: Xylitol in Natural Toothpaste@Pharma joking aside, when I used to work for a manufacturer of white-label toothpaste they used several different grades of abrasive silica; the coarsest one was used for whitening toothpaste, the finest one was used for children’s toothpaste, and the one in between was used for all other kinds of toothpaste
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Bill_Toge
Professional Chemist / FormulatorMarch 4, 2021 at 11:08 pm in reply to: What exactly is Argania spinosa fruit extract?it’s most likely the pulp; the exact nature of the extract will depend on the solvent used, whether it’s water, glycerine, oil, supercritical CO2… -
Bill_Toge
Professional Chemist / FormulatorMarch 4, 2021 at 7:08 pm in reply to: Refrigeration of Vitamin C Serum: Yes or no?to my mind it’s most likely the ferulic acid or the vitamin E; they’re the least water-soluble componentsI’d suggest using a more powerful antioxidant like sodium bisulphite, combined with an excited-state quencher like benzophenone-4 to keep the amount of reactive oxygen to a minimum -
Bill_Toge
Professional Chemist / FormulatorMarch 4, 2021 at 6:40 pm in reply to: Xylitol in Natural Toothpastehow fine is your calcium carbonate? (I’m assuming you’re using that and not metallic calcium)if it’s too coarse, that could easily cause pain and sensitivity -
Bill_Toge
Professional Chemist / FormulatorMarch 4, 2021 at 6:35 pm in reply to: Manufacturing in EU and selling in USthe site has to conform with the same standards as a US-based site, and be accredited by an organisation acting on behalf of the FDA (e.g. SGS)
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Bill_Toge
Professional Chemist / FormulatorJanuary 27, 2021 at 6:09 pm in reply to: How to make body butter glossy and smooth?most likely a difference in processing; you need a high-shear mixer to get creams really smooth
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Bill_Toge
Professional Chemist / FormulatorJanuary 26, 2021 at 11:08 pm in reply to: USA, UK, and every part of the world Sunscreen question?@ngarayeva001 and the percentage is even higher in Liverpool, Newcastle and Glasgow
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Bill_Toge
Professional Chemist / FormulatorJanuary 21, 2021 at 10:03 pm in reply to: One emulsifier or two?as a rule I tend to use two, one with low HLB and one with high HLBwhere possible and appropriate, I tend to add a cationic or anionic as well, just to be sure -
Bill_Toge
Professional Chemist / FormulatorJanuary 21, 2021 at 10:00 pm in reply to: What is causing an allergic reaction in this mask recipe?@Perry in fairness though, if you run it through a gas chromatography machine and it turns out to be a huge mixture of compounds, it’s almost certainly natural
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Bill_Toge
Professional Chemist / FormulatorJanuary 21, 2021 at 9:57 pm in reply to: Updated HLB master list out there?it’s never been an exact science, but it’s definitely a good rule of thumb
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Bill_Toge
Professional Chemist / FormulatorJanuary 21, 2021 at 9:55 pm in reply to: Amodimethicone viscosity for hair conditioningcheck the emulsifiers; in my experience, amodimethicone is usually dispersed in a cationic emulsion, making it completely useless in shampoo
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how much hyaluronic acid have you got, and what’s the molecular weight?
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Bill_Toge
Professional Chemist / FormulatorJanuary 20, 2021 at 11:21 pm in reply to: Updated HLB master list out there?individual manufacturers often supply figures for their own materials, but I don’t know of any recent source that’s compiled all of those figures in once place
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Bill_Toge
Professional Chemist / FormulatorJanuary 20, 2021 at 12:31 am in reply to: How to define a water in oil emulsion?if the product contains a high-HLB emulsifier, you can be sure it’s O/W; it’s not physically possible to form W/O emulsions with high-HLB emulsifiers presenthaving said that, there are numerous products with incomplete or misleading ingredients lists, so the only way to be sure is by physically examining the productthe relative ratio of oil to water is irrelevant - the nature of the emulsion is determined entirely by the nature of its emulsifiers, as there’s no way for the system to ‘know’ how much oil or water is present -
Bill_Toge
Professional Chemist / FormulatorJanuary 20, 2021 at 12:22 am in reply to: What is causing an allergic reaction in this mask recipe?+1 for the strawberry; pentyl butyrate and ethyl methylphenylglycidate, used to create a strawberry odour, are both irritants, while strawberry seed oil is nearly odourless (it certainly doesn’t smell like the fruit) -
Bill_Toge
Professional Chemist / FormulatorJanuary 20, 2021 at 12:14 am in reply to: Inactivation of Preservative by fatty acids,butters, oilsno worries - some specific non-ionic surfactants (specifically, polysorbate-60 or -80) can inactivate certain types of preservatives (particularly parabens); the phenomenon is by no means general
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Bill_Toge
Professional Chemist / FormulatorJanuary 20, 2021 at 12:12 am in reply to: about same surfactant but different supplier problem.your best bet is to use a longer-chain glucoside, e.g. lauryl, myristyl or cocoyl
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Bill_Toge
Professional Chemist / FormulatorJanuary 18, 2021 at 7:19 pm in reply to: Mixing Silicone and Oilmy guess is that the keratin you’re using is a solution in water, which is why it’s not mixing in; what you need to do is find an oil-dispersible form of keratin