Forum Replies Created

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  • Abdullah

    Entrepreneur
    June 15, 2022 at 3:01 am in reply to: pH stability of zinc oxide as skin protector.

    zetein said:

    It has to be higher than 7 and a couple of buffers are needed.
    But why not just buy a bottle of calamine lotion?

    At what pH is calamine stable?

  • Abdullah

    Entrepreneur
    June 15, 2022 at 2:20 am in reply to: pH stability of zinc oxide as skin protector.

    Paprik said:

    I am not sure at this input (1%), but zinc oxide self regulates to pH of around 7 (in SPF or balms products)

    I guess you get a slight skin protective benefits as it covers the skin a bit, but I would not rely on it. 

    Yes for SPF it should be around pH 7. But does it need to be at pH 7 for skin protection too? 

  • Abdullah

    Entrepreneur
    June 15, 2022 at 2:05 am in reply to: pH stability of zinc oxide as skin protector.

    evchem2 said:

    What phase are you adding the zinc oxide to- water or oil?  below pH 6 zinc oxide will start dissolving and you will have Zn ions in solution or new complexes which causes some formulation instability

    I can use it in both phases. I just wanted that skin protection effect of it.

  • Abdullah

    Entrepreneur
    June 14, 2022 at 3:19 pm in reply to: Cream Shampoo Is Expanding in Bottle

    Dont waste your money by adding parabens in shampoo.

  • ketchito said:

    @Abdullah There are actually many patents issued by P&G around the same SH backbone, with few changes. Try using Google patents, and write:  procter shampoo lamellar. You’ll see many entries.

    Thanks

  • @ketchito Is that patented by p&g? 

    If yes, do you know which patent it is so i can have a look. 

  • Abdullah

    Entrepreneur
    June 14, 2022 at 12:00 am in reply to: Reducing Xanthan Gum Tackyness

    Add some gum Arabic

  • Abdullah

    Entrepreneur
    June 13, 2022 at 4:26 pm in reply to: Understanding Emulsifiers

     Are you saying that the GMS SE and cetyl alcohol may be reducing the viscosity of this one emulsifier, but not the others?

    Maybe. If you make a batch with only 202 then you can say for sure what was the problem. 

    In LGNs only a specific ratio of surfactants give high viscosity as shown here. 

  • Perry said:

    I mean that whenever you change any aspect of the composition of a surfactant system (e.g. concentration, surfactant type, etc), the viscosity response to salt addition will change.

    Got it
    Thanks

  • @Perry you mean if a formula has only 10% SLES and another formula has only 5% SLES, salt response will be different between these two formulas? 

  • Abdullah

    Entrepreneur
    June 13, 2022 at 12:42 pm in reply to: Glyceryl Oleate

    Maybe you are using too much GMO or too little surfactants. 

    It is liquid and it doesn’t need heating to mix with surfactants

  • ketchito said:

    @Abdullah You should feel a difference with a Guar HPTC formula…maybe you need to increase the level. Also, you could add some silicone (same principle as in hair).

    I definitely see a difference in foam but I can’t notice any difference on my skin. 

    What type of effect should i look for in guar Hydroxypropyltrimonium Chloride in skin cleanser?

    For hair i am using Amodimethicone. 
    I have experienced that if i used Amodimethicone too much or in wrong way in shampoo, it irritates the scalp. Is it safe to use Amodimethicone in skin products?

  • I’m just a student and maybe I’m talking nonsense, but I think that the needs and therefore the conditioning mechanisms are not the same for hair or skin, so there are no exact analogs. I understand that hair conditioning depends more on aspects such as pH, ionic charge (and that is why cationic substances are used) or the closing of the cuticle. In a shampoo I understand that the type of surfactants used also makes a big difference (I don’t have much experience but I have achieved results that I really like using a combination of anionic, non-ionic and amphoteric surfactants). I would also add some refatting agent, and some active ingredient (I personally love the effect of inulin).
    In the case of skin, I believe that conditioning depends on maintaining and reinforcing the barrier function of the skin so it is important that the mixture of surfactants is effective but gentle (and in lower imputs than in shampoos), and at least, a refatting agent and a moisturizer should be incorporated, or even an very small imput of a lipid. It doesn’t make sense to me to use a cationic ingredient in a face or body wash.
    I find that anyway it is not a single product that achieves the result, but the proper combination and proportion of all of them.

    Thanks

  • Abdullah

    Entrepreneur
    June 13, 2022 at 8:58 am in reply to: Glyceryl Oleate

    What is your formula, method and what problem are you facing?

  • Abdullah

    Entrepreneur
    June 13, 2022 at 3:41 am in reply to: Understanding Emulsifiers

    What is your pH? 
    Is that 0.02% xanthan gum? 

    I would say use 0.2-0.3% xanthan gum.

    Also ratio of surfactants have big impact on viscosity. As you dont know the composition of m 202, why don’t you make a batch with only 202 and remove GMS SE & fatty alcohol?

    I am sure the ratio in 202 is optimized to give high viscosity. 

  • Abdullah

    Entrepreneur
    June 12, 2022 at 12:02 am in reply to: Understanding Emulsifiers

    Pharma said:

    A: Montanov 202 and glyceryl stearate SE have a higher melting/processing temperature than the other ones (~10°C higher). Generally, 70°C is on the lower end for all of them. Try 80°C.
    B: Montanov 202 is also different insofar as it can handle higher amounts of oils or rather is meant to be used with considerably higher oil phases.
    C: The four emulsifiers all result in lamellar gel networks rather than micellar emulsions; hence, they may not take too high too long shear mixing (especially under the ‘gelling’ temperature) very well.
    D : Because of point C, all these emulsions will ‘ripen/harden’ over the next few hours to days. Give them some time to fully attain their final viscosity. Cooling rate can also be part of the difference (M 202, because of point A, doesn’t do well when cooled too fast and can’t ripen in the worst case).

    Is gelling temperature below 50°c temperature?

  • Abdullah

    Entrepreneur
    June 10, 2022 at 11:51 am in reply to: How to determine CMC of mixed surfactants in a cleansing product?

    ketchito said:

    @Abdullah Indeed, total free surfactant below CMC wouldn’t necessary be the sum of each free surfactant, measured separately.

    That is good to know.
    Thanks

  • @grapefruit22 Pantene shampoo that i purchased from UAE had better conditioning effect when hair was wet & dry compared to my shampoos. 
    Maybe it is how different do dimethicone and Amodimethicone feel from Shampoo. I use Amodimethicone and Pantene had dimethicone.

    My shampoos are better than almost every local shampoo that i have tested. 

  • Abdullah

    Entrepreneur
    June 10, 2022 at 3:47 am in reply to: SLES upper limit in rinse off and leave on products?

    If you want, I could show you how to check things like this on CosIng .. EU database :) SUSMP for AUS is a bit tricky to use, but also handy. 

    Sure i want

    I sometimes wonder why are they not specifying some limits but they are there.

    For example dimethicone is OTC skin protector. They don’t say which viscosity so that should mean any viscosity is. But in reality viscosity ≥350 is skin protector, not lower.

    Same for SLES, from experience during manufacturing our products, i know that 70% SLES, can be damaging the skin. 

  • Abdullah

    Entrepreneur
    June 10, 2022 at 12:22 am in reply to: SLES upper limit in rinse off and leave on products?

    Paprik said:

    As there are no regulatory limits (EU, AUS), I’d say 100%. I believe that is how they were testing the ingredients, neat on the rabbits ears and wait. Or submerge them into solution and wait. 

    Thanks ????

  • Abdullah

    Entrepreneur
    June 9, 2022 at 4:36 pm in reply to: Moisturizing body wash trouble

    What is the purpose of this product?

    What benefits you want to see and why you want to make such a product?

    A simple cleanser with just 4-5% SLES will be a better cleanser and less drying and much less expensive that your product.

    Your problem maybe not enough heating or too much surfactants. 

  • ggpetrov said:

    Abdullah said:

    ggpetrov said:

    Abdullah said:

    @ggpetrov What percentage of emulsifiers did you use?

    1 Usually I use about 3%, but I always pair the emulsifiers. 

    Thanks 
    For me BTMS dry and powdery feel was noticable from 0.5-1% BTMS. What percentage of pg3 stearate will have that feeling of 0.5-1% BTMS if it can have it al all?

    I’ve just looked at my worksheet. 2% Softfeel PS + 0.5% GMS Citrate + 1% Cetearyl alcohol and 8% fat phase. Also I have used 0.2% Sodium Carbomer. Keep in mind that Softfeel tends to thicken the emulsion, so with this incredients I’ve got a thick lotion. The sensorial properties of the emulsion are wondefull. You have enough playtime, but when you finish, the emulsion dissapears literally. The feeling is that you have nothing on your skin, and even more you almost can’t leave a fingerprints on the objects. Meanwhile the skin is fresh and soft.

    Thanks 
    That is the type of feeling i like too.

  • Abdullah

    Entrepreneur
    June 9, 2022 at 12:22 pm in reply to: How to determine CMC of mixed surfactants in a cleansing product?

    @ketchito thanks 

    My point was aslo just to know if the amount of free surfactant below CMC of each surfactant will interact and make micceles so total free surfactant is not the same as the sum of total free surfactant of each surfactant. 

  • Abdullah

    Entrepreneur
    June 9, 2022 at 12:02 pm in reply to: SLES upper limit in rinse off and leave on products?

    Leaving SLES on skin doesn’t have any benefit for skin but we can guess how mild it is.

  • Abdullah

    Entrepreneur
    June 9, 2022 at 1:49 am in reply to: How do several surfactant in a product arrange to form a micceles?

    Perry said:

    On average, perhaps. In any specific instance, perhaps not.
    You may be taking the metaphor of a micelle a bit too seriously. They do not last in some specific form for any extended period of time.

    Thanks

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