

MarkBroussard
Forum Replies Created
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MarkBroussard
Professional Chemist / FormulatorApril 6, 2020 at 1:22 pm in reply to: Please help! Hand sanitizers formulaPerhaps there is a forest somewhere in all these trees!
The main issue is the contact time required for the alcohol to denature the viral proteins which is in the range 20 to 30 seconds. It really does not matter if you use a spray or a gel. Simply spray 1 pump wait 15 seconds, spray another pump. Or, use a gel.
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MarkBroussard
Professional Chemist / FormulatorJanuary 21, 2020 at 11:03 am in reply to: help a chemist out 🙂Your Phytic Acid content is quite high at 2%. You might want to consider add the Phytic Acid at the end to adjust the pH to your desired end-point.
Tocopherol Acetate … does absoultely nothing … better to use mixed tocopherols or tocotrienols.
Phase 2: Your total oils/butters is 20%. I would recommend cutting that back to a total of 12% … it will give you a smoother feeling emulsion.
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MarkBroussard
Professional Chemist / FormulatorJanuary 12, 2020 at 2:54 pm in reply to: Humectants: Which one is preferable?The nice thing about the glycols is that you also get some preservative boost in addition to moisturization/humectancy.
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MarkBroussard
Professional Chemist / FormulatorJanuary 11, 2020 at 2:20 pm in reply to: Humectants: Which one is preferable?If this is a cream, you can use glycerin at up to 5% without any sticky afterfeel … all depends on what else is in your formula.
Glycerin + Propanediol or Pentylene Glycol or Butylene Glycol
If you want to avoid using Glycerin you could use Sodium Lactate, Sodium PCA … as mentioned above Betaine or any combination of all of these.
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MarkBroussard
Professional Chemist / FormulatorJanuary 3, 2020 at 5:02 pm in reply to: Honey and Oil Facemask Preservative + emulsifier?Honey is water-soluble, so just treat it like it was your water phase and use any appropriate emulsifier for the type of emulsion you are trying to create … O/W or W/O.
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MarkBroussard
Professional Chemist / FormulatorJanuary 3, 2020 at 1:50 pm in reply to: Anti-inflammatory extracts and topicals - what works best?Most reputable suppliers sell extracts as either a 50%/50% mix of Glycerin/Water + 8% Extract. If you are loading in 1% Extract blend, which is common, you’re actually winding up with a miniscule amount of actual extract in the formula.
As Perry mentioned, if you want an effective formula, look to add the individual compound derived from the extract that has proven to be effective.
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MarkBroussard
Professional Chemist / FormulatorDecember 31, 2019 at 3:37 pm in reply to: Serum versus other formulation typesThe concept of a “serum” is a simple formula containing few “active” ingredients in higher concentration than you normally find in creams, etc. As Perry mentioned, they are generally quite viscous.
A serum is a very direct, clean formula that generally dispenses with unnecessary claims ingredients and just focuses on the ingredients that achieve the desire effect. Yes, they are relatively simple to develop and manufacture.
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MarkBroussard
Professional Chemist / FormulatorDecember 31, 2019 at 3:02 pm in reply to: What are the best essential oils in term of good for skin and good scent?IMHO … neither Essential Oils nor Fragrance Oils serve any benefit to the skin other than scent. So, your tradeoff is something thing that smells good, but also has negative effects on the skin such as photosensitization and/or allergic reaction and really no benefits. But, scent is an important product feature for many consumers.
EO’s and Fragrance Oil most often contain some of the same chemical compounds, so one is not really any better than the other.
Case in point … I recently had a custom fragrance developed that excluded the known fragrance allergens … in working with it, some spilled on a stained concrete floor … it actually dissolved the stain. I’ve never had an essential oil do that.
As general guidance, EO’s from citrus are the most photosensitizing. Floral EO’s tend to be less irritating to the skin. So, Rose, Lavender, etc.
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MarkBroussard
Professional Chemist / FormulatorDecember 31, 2019 at 12:55 am in reply to: Is it possible?Yes, just trial and error the % until you get something your test panel likes. Make a 5% batch and see how your customers like it.
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MarkBroussard
Professional Chemist / FormulatorDecember 30, 2019 at 1:51 am in reply to: Is it possible?2% or so Cetrimonium Chloride is a good place to start
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MarkBroussard
Professional Chemist / FormulatorDecember 29, 2019 at 3:31 pm in reply to: Difference in formulation between “medical-grade skincare” and over the counter brandsI’ll add that there is no category “Medical Grade” cosmetics … “Medical Grade” is a marketing term implying that some of the ingredients used in the product are USP-grade as opposed to Cosmetic-grade
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MarkBroussard
Professional Chemist / FormulatorDecember 29, 2019 at 3:08 pm in reply to: PAO - The Period After OpeningPAO applies to products with a shelf life of 30 months or more … if your product requires a shelf life of 30 months or more, you have a sales & marketing problem, not a product stability problem. For most consumers, the PAO is when the container is completely empty after they have used all of the product.
This reminds me of the expiration date on fresh food products … it’s an estimate of “peak” freshness, but supermarkets discard tons of perfectly good food products daily when this expiration date is hit. Such a waste.
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MarkBroussard
Professional Chemist / FormulatorDecember 28, 2019 at 3:58 pm in reply to: Difference in formulation between “medical-grade skincare” and over the counter brandsI’ll note that all of these brands also sell their products through online channels … diluting the “professionals only” channel strategy. But, presumably they get a boost in consumer’s perception of effectiveness if they are carried in physicians offices and recommended by physicians and estheticians.
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MarkBroussard
Professional Chemist / FormulatorDecember 28, 2019 at 2:30 pm in reply to: Difference in formulation between “medical-grade skincare” and over the counter brandsNope … no difference. It’s a marketing/sales channel strategy that does not have anything to do with the products. There may be some occasions where some ingredients in certain products must be dispensed by a physician, but that would not be common with the lines you have listed in your note.
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MarkBroussard
Professional Chemist / FormulatorDecember 27, 2019 at 6:13 pm in reply to: Formulating Dry (not liquid) Skincare Products?The reason you mostly see this approach with LAA is due to its instability in solution.
Mixing LAA powder into a serum immediately before use ensures you don’t get degredation of the Vitamin C over time. Yes, you can add other powder ingredients along with the Vitamin C provided they are readily soluble in water, unless you want the end user consumer to spend some time heating and/or mixing the product … For instance, Hyaluronic Acid would not work, nor would Allantoin.
The most interesting line in the article is that the combination of Tyrosine and Zinc increased the bioavailability of LAA by 20-fold.
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MarkBroussard
Professional Chemist / FormulatorDecember 27, 2019 at 4:07 pm in reply to: Is a humectant essential in a face wash formula? And questions about options.@MJL :
Adding a humectant or refatting agent to a face wash is more beneficial from the perspective of the skin afterfeel … the skin does not feel so “squeaky” clean … you’ll feel this more on your hands than on your face.
Yes, you can use Sodium Lactate in a cleansing product … the issue is that the surfactants are going to do their job and wash off most of it, so it goes down the drain and not on your face.
Better to just create a simple, gentle cleanser and then apply a moisturizing serum or cream after cleansing.
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MarkBroussard
Professional Chemist / FormulatorDecember 26, 2019 at 3:21 pm in reply to: Replacement for Calcium Carbonate in Natural TootpasteThe way to figure out your issue is to run your powders through a 20 uM sieve. Regrind the residual that is trapped by the sieve … these particles are too large to pass through the sieve and get trapped. Keep doing this until all of your desired volume of powder runs through the sieve. You’ll then know you have a distribution of particle sizes of no greater than 20 uM.
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MarkBroussard
Professional Chemist / FormulatorDecember 25, 2019 at 10:20 pm in reply to: shampoo formula, high porosity. any tips?Correct: Betaine = Trimethylglycin … it’s an osmolyte that helps to retain water and penetrates the hair shaft.
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MarkBroussard
Professional Chemist / FormulatorDecember 24, 2019 at 11:31 pm in reply to: shampoo formula, high porosity. any tips?Add 4% Betaine and 0.5% Babassu Oil or 0.5% Coconut Oil and that will help tame the frizzies.
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MarkBroussard
Professional Chemist / FormulatorDecember 24, 2019 at 2:24 pm in reply to: learning about % in formulasGeneral Guidelines:
Plant Extracts 1% or less
Emulsifiers 2% to 4%
Fatty Alcohol Thickeners 2% to 3%
Gums 1% or less
Preservatives 1%
Surfactants 20% for primary, less for secondary surfactants. Shoot for a total surfactant load of 35% to 45%.If you are trying to dupe formulas by looking at list of ingredients, try to find the “!% line” … this will generally be a preservative, but not necessarily so. Regardless, if you find the 1% line … that is an ingredient most likely added at 1%, then all ingredients below that are added at less than 1% and all ingredients that preceed it are loaded at greater than 1% and are in descending order ranked from highest percentage to lowest percentage. As to how much of each, it’s an educated guess.
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MarkBroussard
Professional Chemist / FormulatorDecember 24, 2019 at 2:10 pm in reply to: shampoo formula, high porosity. any tips?Water QS to 100
Slippery elm 1
Aloe Vera 10
Coco betaine 10
Sodium Cocoyl Glutamate 20
Apple cider vinegar 3
Citric acid QS to adjust pH to 5.6
Shea butter .05 to 1 (maximum)
Silk protein 1
Wheat amino acids 1
glycerin 3
Cetyl alcohol DELETE
Xanthan Gum 0.5
Preservative of your choice
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IMHO … CBD has utility in pain relief topical products, but personally I think it is quite useless as an ingredient in a skincare “beauty” cream that is not intended for pain management.
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MarkBroussard
Professional Chemist / FormulatorDecember 23, 2019 at 2:24 pm in reply to: Shampoo SurfactantsYes, you could make a shampoo with only those two surfactants. You might start with 20% SCI and 10% CCG and see what foam profile you get and adjust from there, but those are good starting points.
It is easiest if you grind the SCI into a fine powder, disperse it in cold water with stirring, and then heat it to 80C until all SCI is melted.
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MarkBroussard
Professional Chemist / FormulatorDecember 20, 2019 at 12:29 am in reply to: Shea butter glyceridesIt is unfortunate, but re-packers like MakingCosmetics often modify the INCI to make it a bit different from the ingredient manufacturers that they purchase product from. Presumably, part of the re-packer distribution agreement is that they cannot use the manufacturer’s INCI is the only reason that I can fathom. It’s not all of their products, but some products that have a different INCI from the original product manufacturer’s INCI.
The proper INCI is Shea Butter Glycerides and the manufacturer is Jarchem Innovative Ingredients.
Yes, they work just fine … 3% yields a nice cream. I find them difficult to work with at higher levels as they tend to separate from the water phase.
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MarkBroussard
Professional Chemist / FormulatorDecember 19, 2019 at 11:17 pm in reply to: Poly Suga Mulse D9 is not a real emulsifier?Poly Suga Mulse D9 is a fragrance solubilizer … no, it’s not really an emulsifier per se.