Home Cosmetic Science Talk Formulating The ion charge order of surfactants

  • The ion charge order of surfactants

    Posted by Henry on June 22, 2021 at 12:26 am

    I was told that anionic surfactants may have their order of addition by their anionic charge for a shampoo.  what does that mean and how do I determine the charge and the addition rank?

    Henry replied 2 years, 10 months ago 2 Members · 4 Replies
  • 4 Replies
  • chemicalmatt

    Member
    June 24, 2021 at 6:49 pm

    @Henry that dictum applies whenever you are building a conditioning shampoo with cationic materials or when employing an acrylate copolymer thickener. Otherwise you can add in any order you like, there is not much difference in zeta potential so much as there is in activity levels.

  • Henry

    Member
    June 25, 2021 at 3:04 pm

    @chemicalmatt -thank you… I am still confused. is there a rule of thumb about order of addition for shampoos. and with  acrylate copolymer.  

  • chemicalmatt

    Member
    June 25, 2021 at 4:00 pm

    That will be formula dependent @Henry. If no cationics are present,then add your anionics (e.g. SLES, Na sarcosinates, etc.) first, then nonionics, amphoterics, builders. When using multiple anionics, add the least soluble one first (i.e. sarcosinates).

  • Henry

    Member
    June 25, 2021 at 6:18 pm

    If I had cationics…. with anionic surfactants….I should add those last?  Thank you again.

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