

ngarayeva001
Forum Replies Created
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ngarayeva001
MemberJanuary 28, 2023 at 6:39 am in reply to: How to apply pigment to liquid based cosmeticsOn a separate note, the cream format of blush and highlighter (provided it’s mixed in a store, not by a consumer) can be relatively easy.
I make several hundred grams of cream blush base and mix it with liquid pigment when I fancy a new colour.
INCI % Ricinus Communis (Castor) Seed
Oil41% Hydrogenated
Polyisobutene10% Bis-Diglyceryl
Polyacyladipate-213% Polyhydroxystearic
acid2% Euphorbia
Cerifera (Candelilla) Wax7% Microcrystalline
wax5% Polyethene
wax3% Pigment blend 20% The base is 80% of the final product. The pigment is usually 50% diisostearyl malate 50% (made by me) or premade blends I buy from TKB
https://tkbtrading.com/products/the-diy-chocolate-lip-liquid-color-set?_pos=4&_sid=dcebe910a&_ss=rPlease don’t use that formula for commercial purposes because I created it to mimic a particular product for personal use. I would formulate it differently if it weren’t for personal use. It doesn’t have a proper preservation system (not ok for commercial), and I didn’t add antioxidants because I don’t add fragrance (you won’t get away with that for a commercial product).
A similar approach might be applied to cream eyeliners, provided it is mixed by a trained consultant in a shop, not by the consumer. Eyeliner must be formulated by a professional, and much thinking must be put into preservation as it is applied close to the eyes. Again formulating a chassis is not the same as formulating a one-off product. It must have some room for error.
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ngarayeva001
MemberJanuary 28, 2023 at 6:15 am in reply to: How to apply pigment to liquid based cosmetics2) Another idea can be using microencapsulated pigments like the one below https://www.glamourcosmetics.it/it/surprise-color-set (sorry don’t know who is the manufacturer).
You can create a base with TiO2 and provide those encapsulated pigments in a separate packaging to mix as the person applies (put some base on a back of a hand, add microcapsules mix with a sponge/brush) it but you need to think through the measuring system (how much to add? you would need a light version, a dark version and pink version again).
A lot of thinking is required here but it would definitely impress the consumer. I believe Clinique used microencapsulated pigments in one of its products.
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ngarayeva001
MemberJanuary 28, 2023 at 6:07 am in reply to: How to apply pigment to liquid based cosmeticsSo, a couple of ideas to bring the “DIY” vibe to the product.
1) https://www.glamourcosmetics.it/it/gc-base-bb-cream-creamy-nude
This is a premade foundation pigment blend. The supplier is The Innovation Company https://theinnovationcompany.fr/en/products/creasperse-bb/You can create a foundation base using the lightest neutral colour (or even white) and provide, say, 3 small bottles of pure liquid pigment blends 1) dark neutral, 2) pink undertone, and 3) yellow undertone. I can’t emphasise liquid enough. Please don’t mess with the dry powder; it will not end well (the consumer won’t be able to mix it). The innovation company sell relatively small quantities (I emailed them several years ago, and they agreed to 10kg). 10kg was not what a hobbyist needs, so I found the Italian repackager listed above. They, unfortunately, only have two shades, but you can buy a small bottle to test it before going to the original supplier.
Having said that, you have to be very clear with the formulator who will create the base that it is a base and it will be mixed with something else. It absolutely must be accounted for during the product development (more preservatives, etc.).
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ngarayeva001
MemberJanuary 26, 2023 at 10:20 am in reply to: How to apply pigment to liquid based cosmeticsThere’s a couple solutions to this (for foundations) but you would have to give up on dry powder idea. I will share a couple of links later today.
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ngarayeva001
MemberJanuary 26, 2023 at 10:13 am in reply to: is it a good start for a lotion cleanser?In my personal experience the only format that cleanses and moisturizes at the same time is balm. Surfactant and oil. Banila, Clinique take the day off etc.
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ngarayeva001
MemberJanuary 25, 2023 at 7:08 am in reply to: How to apply pigment to liquid based cosmeticsShort answer: not feasible at all.
Lond answer:I don’t know where to start as this topic is endless, so l will stick to one product I have more experience with: foundations.
Foundations pigments are made of TiO2 and three iron oxides (yellow, red, and black). No consumer would be able to mix those three themselves to obtain their “perfect colour”. Ask an artist who paints portraits how long it took them to figure out how to mix human skin colour.
These pigments are not easy to mix. They must be treated (say with methicone) to mix with oil. You need the right type of oil. You need dispersing agents such as polyhydroxystearic acid and hectorites to make it work. You need special equipment (three roll mills etc) to make it work. It’s problem after problem after problem. You solve one, and another arises.
Also, foundations are mostly W/Si. W/Si are fussy structures. If your customer adds more of the pigment blend than that base could take, it will separate. If not right away it will do it in a week. If not in a week in a month. The customer won’t be happy.
To summarise, there is a lot to it. It’s not the same as mixing paint, unfortunately.
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Some tips and tricks:
1) think through your preservation system. I formulate in my kitchen and although I bathe my working area in bleach and use outrageously overpriced steam-distilled water (which I also boil just in case) I can only trust “toxic chemicals” when it comes to preservation. Phenonip, phenonip, phenonip. Phenonip is a blend of parabens and phenoxy. Parabens are prone to partitioning to the oil phase, so you want to heat it. That’s why I am not big on cold process w/o. Even if I have nothing to melt, I heat my water to ensure parabens don’t migrate to the oil phase.
2) I generally prefer PEGs but there are actually pretty decent PEG-free w/o emulsifiers. I like Emullium Illustro by Gatefosse, PolyAquol VO4 and Isolan GPS. Having said that I am still a big fan of w/si and Dow’s Formulation Aid 5225 and PEG-10 Dimethicone are great. PEG-30 DPHS with magnesium stearate in the oil phase makes a beautiful texture and is more or less easy to make right from the first attempt.
3) Always start with the supplier’s suggestions when it comes to %. When it comes to the process, I follow the standard w/o approach: overhead stirrer, water added by drops (takes ages), homogenise when cools down. If viscosity increased after you applied high shear, you did it right (not a rule but it’s usually a good indicator).
4) Already been suggested by more experienced people but I will repeat: salts in the water phase, gellants in the oil phase. Magnesium stearate is a good one (needs to be heated to dissolve). I don’t like the waxy feel, so often search for alternative solutions to several % of wax in the oil phase, but that is playing with fire. My current favourite is a combination of Stearyl Dimethicone and silica (or silica dimethyl silylate). Obviously, 3-5% of hydrogenated castor wax is a much more reliable approach.
5) skip water phase gellants unless you are making seppic’s gel trap (which is weird anyway).
6) Start simple. Don’t overload it with actives. Your goal is to make it stay together. Only start adding actives after you “know your formula”.
7) Be thoughtful of emollients (oil phase). I would stick to the supplier’s recommendations in the beginning.
I probably forgot something, but if you go w/o a route you can ping me.
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I guess many people here know of my weird obsession with w/o emulsions. I always advise against w/o because you must have a reason to take w/o route. For some, that reason is creating a formula for a client. For me, it’s just a weird desire to fight against the second law of thermodynamics (knowing well in advance who is going to win). Jokes aside, happy to help you to fix w/o formula if you are persuaded it’s what you need. I think you are just after an occlusive o/w or maybe even a balm, not actual w/o. They are fussy. Took me hundreds of attempts to get them right. Get them right here meaning not separating for over 18 months stored in a cupboard and looking somewhat decent under a microscope. I am a hobbyist and don’t run proper stability tests.
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ngarayeva001
MemberJanuary 25, 2023 at 6:14 am in reply to: As a professional chemist, what skincare products you DIY for personal usage?@Herbnerd that toothpaste sounds nasty for adults but having a 5 year old I must say you are very wrong about marketing. It just needs to be marketed to kids. Parents would buy anything to make their kids brush their teeth. Imagine Halloween variations? I think you found a niche to explore:)
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ngarayeva001
MemberJanuary 23, 2023 at 2:46 am in reply to: As a professional chemist, what skincare products you DIY for personal usage?@toketsu by the way, you can find almost any ingredient in small quantities if you are willing to pay for shipping and prepared to get them from different places. Any o/w would be cost effective to make even if you get ingredients from 5 different countries because commercial products have insane margins. Surfactant products are usually more cost effective to buy. You also don’t need special equipment unless you make w/o. The main expense are scales and pH meter (good quality Chinese would do).
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One important thing, if that’s w/o preservative added to cool down phase won’t be very effective: your external phase is oil. You need to preserve water.
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OliviaLeigh said:Okay so here goes :#
Heated Oil phase 75
Cetearyl alcohol 5%
Candellia wax 5%
Rose wax 1.5%
Murumuru Butter 8%
Mango Butter 5%
Shea Butter 3%
Grapeseed Oil 16%
Camellia Oil 4%
Coco-caprylate-caprate 5%
Arrow Root 1%
Lecithin (sunflower) 2%
PG4-O 8%
Heated Water Phase 65
Hydrosol 20%
Distilled water 10%
Rice starch 1%
Glycerite 1.5%
Cool Down Phase 40
Preservative 12 1%
Sea Buckthorn CO2 0.5
Sodium Hyaluronate Gel 2.5 (1% HA)
Eo blend will be added later under 1%
Sorry but if it’s w/o there’s a lot that is wrong with it. Let’s start with challenging the concept: do you actually need w/o? You can make an occlusive o/w with very high oil phase.
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W/O emulsions are not stable by nature. Unfortunately 2 months isn’t enough to conclude. Please post the formula because from the description of ingredients something doesn’t sound right.
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ngarayeva001
MemberJanuary 15, 2023 at 8:33 am in reply to: How to identify electrolyte-containing ingredientsSalts are usually strong electrolytes and are made when acid reacts with metal. So look for a metal in the name: Sodium, Potassium, Magnesium etc.
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ngarayeva001
MemberJanuary 15, 2023 at 8:16 am in reply to: Can you help me decide on an emulsifier combo?Combination of EMT10 and Zen can stabilize even high oil phase and won’t cause any soaping at all. You can even add some cetearyl alcohol and other waxy materials to make it feel more substantial.
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If various creams are o/w emulsions you don’t need overhead stirrer at all. You need high shear to ensure droplets are small. Get a powerful stick blender (600W +). Bosch has good options. Regarding surfactant products, you can mix them by hand. Overhead stirrer won’t be able to mix viscous shower gel unless it’s very powerful and costs way over 1,500 euros. The only reason someone who is formulating at home might want to get an overhead stirrer is for w/o emulsions or dissolving polymers.
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What’s the wattage?
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To me the less ‘natural’ fluff it contains the cleaner
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ngarayeva001
MemberJanuary 10, 2023 at 6:40 am in reply to: SLES or Disodium laureth sulfosuccinate?The latter is pH sensitive and quickly decomposes in acidic environment.
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If your question is which of the listed ingredients feel subjectively more waxy then myristyl myristate and cetyl palmitate would feel more ‘waxy’ at 3% concentration in o/w emulsion with 10% oil than C10-18. Source: my anecdotal opinion based on my kitchen tests of all three (and a couple of others). Having said that everyone’s perception is different
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Yes, you can heat it. You can also heat lower viscosity dimethicone (down to 5)
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ngarayeva001
MemberJanuary 9, 2023 at 9:22 pm in reply to: As a professional chemist, what skincare products you DIY for personal usage?Not a professional but since it’s my hobby it’s easier to list what I don’t make: 1) mascara because it’s messy 2) eyeliner (see mascara) 3) powders because I don’t have a press and don’t want to buy one. 4) sunscreen because it must be left to large corporations with a testing budget. I stopped making shampoos, showergels and deodorants because I don’t have enough time and it’s easier to buy these products.
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ngarayeva001
MemberDecember 12, 2022 at 8:26 am in reply to: Formulating a cleansing oil for the very first time@Ducq I mix 15% of polysorbate 80 with high polarity ester (either alkyl benzoate or some types of CCT) and use it as cleansing oil to remove makeup including mascara. It got into my eyes on a multiple occasions and I didn’t even need to blink. More popular Cithrol 10 GTIS is more irritating. Totally anecdotal, and I am open to be proven wrong. But the article above doesn’t prove anything.
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ngarayeva001
MemberDecember 12, 2022 at 8:17 am in reply to: Formulating a cleansing oil for the very first timeGhita37 said:Hello @ngarayeva001 thank you for your response.
Of course- here is one link i read on Polysorbate 80 skin irritation effects.https://thedermreview.com/polysorbate-80/
There was another article i read but i cant remember the name.If i find it ill share itThis article is a perfect example of what a good source should not look like. Not only they make claims without supporting it with scientific evidence they also immediately suggest an alternative product to buy. It doesn’t prove Polysorbate 80 is irritating. It proves that those who wrote the article are biased and use fear marketing. Don’t get me wrong poly 80 isn’t a one size fit all perfect solution. But it is an old but gold bullet proof ingredient that is well researched, cheap, easily available and pretty multifunctional.
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ngarayeva001
MemberDecember 7, 2022 at 7:43 pm in reply to: C 12-15 AB vs C 12-15 Alkyl Lactate … compare please.Alkyl benzoate is that one ingredient I always have in stock. As multi purpose as it gets. Helps disperse EOs in silicones, compatible with polysorbate 80 in oil cleansers, light yet not drying.