Home Cosmetic Science Talk Formulating General Let’s compare humectants!

  • ngarayeva001

    Member
    June 30, 2020 at 10:34 pm

    Sodium Lactate. More hygroscopic than glycerin, probably the least sticky of all I tried. On the negative side, it’s a salt - can’t be used with polymeric thickeners based on acrylic acid (carbomers, aristoflex avc etc). Butylene Glycol for sensitive materials. Less sticky than glycerin, compatible with many ingredients, preservative booster (reduces water activity). What I couldn’t find my way around is isopentyldiol. Had huge expectations (it was told to dissolve SA better than propylene glycol) but it disappointed me. Exploring urea currently.

  • esthetician922

    Member
    June 30, 2020 at 10:41 pm

    @ngarayeva001

    I need to start wearing a mask when I formulate with SL, I can taste salt for hours. 
    Never heard of isopentyldiol….what is SA?

  • ngarayeva001

    Member
    June 30, 2020 at 10:48 pm

    Oh, you mean powder! I have never bought it for some reason. I use a liquid which is usually  60%. Isopentyldiol is a glycol, I just fell after supplier’s info again. If someone thinks it’s a good material and I am wrong please let me know. It’s more expensive than propylene glycol but I couldn’t see any difference. SA is salicylic acid.

  • esthetician922

    Member
    June 30, 2020 at 10:58 pm

    Hmmmm any benefit using liquid SL over powder? 

  • OldPerry

    Member
    June 30, 2020 at 11:09 pm

    Glycerin. Price, compatibility, effectiveness…it’s hard to beat.

  • ngarayeva001

    Member
    July 1, 2020 at 5:51 am

    My general approach is that is someone had predisperced that I would rather get a liquid form. Had negative experience with trying to dissolve things myself (tried to dissolve trimethylsiloxysilicate in isododecane to save money: never again). Also as you noticed powders are floating around in the air and I hate wearing masks.

  • LincsChemist

    Member
    July 1, 2020 at 4:34 pm

    I agree with Perry, it’s hard to beat glycerin - I’ve seen some decent data for Betaine but it was provided by a supplier so it’s to be taken with a pinch of salt. Seems to work quite nicely though and it lowers the tack if you use it in combination with glycerin.

  • Pharma

    Member
    July 1, 2020 at 7:25 pm
    I also like choline (though the fishy smell is quite pronounced :disappointed: )… weird enough that in some countries (Canada, if memory serves me right) it is still not allowed in cosmetics due to some old and false data..
    Proline is also nice but very pricey.
    Did someone already mention sorbitol (not my favourite but way less tacky, nice in hydroalcoholic gels)?
    I usually use blends to reduce unwanted effects.
  • ngarayeva001

    Member
    July 1, 2020 at 9:00 pm

    I bought sorbitol recently but can’t decide whether I like it or not. Btw betaine helps with dissolving SA a little. I know I sound like dissolving SA is my biggest problem ????

  • esthetician922

    Member
    July 1, 2020 at 9:56 pm

    Do you guys test a humectant on its own in water first before adding anything to it to see if you like the feel? I am guessing the feel will change as you add more ingredients. 

  • jemolian

    Member
    July 2, 2020 at 12:32 am

    I have quite a few different humectants, though normally i’d just use in combination of Glycerin + Betaine. Addition of Trehalose if i’m feeling fancy.

    The glycols / diols make my face tingle a little, so i try not to use them too much or often. For other sugars, i have Aquaxyl, Sorbitol, Erythritol as well. I can’t really use Urea since it kind of exfoliates me too much.  

  • ggpetrov

    Member
    July 2, 2020 at 7:13 am

    In addition to the ngarayeva001‘s suggestions I would add Pentylene Glycol, Sucrose Stearate, Inulin. I am in love in the Inulin, ofcourse I can’t prove its efficacy, but the feeling when in the emulsion has the Inulin is fantastic!

  • Ifa

    Member
    July 11, 2020 at 8:44 am

    I agree with Perry, it’s hard to beat glycerin - I’ve seen some decent data for Betaine but it was provided by a supplier so it’s to be taken with a pinch of salt. Seems to work quite nicely though and it lowers the tack if you use it in combination with glycerin.

    What combo seems to work best for you?

  • amitvedakar

    Member
    July 12, 2020 at 5:12 am

    what about aquaxyl+glycerin combo.

  • Zink

    Member
    July 16, 2020 at 6:47 pm

    How about Saccharide Isomerate? 

  • joowan11

    Member
    July 16, 2020 at 9:05 pm

    Zink said:

    How about Saccharide Isomerate? 

    It’s not really that amazing, the only data I saw was by DSM, which is the manufacturer. Also, it’s expensive.. I might use it for “omg 72h hydration your mother will be shocked” claims but glycerin is always there for you and it costs next to nothing

  • helenhelen

    Member
    July 21, 2020 at 9:57 am

    I been trying a few different humectants lately…

    Erythritol leaves a horrible tackiness.. I really didn’t like it.

    Betaine doesn’t leave as comforting a feel as glycerin. The hydrated moistness of the skin doesn’t last as long as with glycerin (it evaporates off shortly after) and it has a sort of sliminess when the skin is rinsed later. 

    I bought some sodium lactate liquid but it felt very tacky on the skin when I tried it neat… more so than neat glycerin (to me anyway). It’s less thick, but there is still a tacky afterfeel that doesn’t go away.

    Floraesters K-20W Hydrolysed Jojoba Esters helps to reduce glycerin tack and reduce the amount of glycerin needed (thanks for the tip @Graillotion - I tried it before but got much better results this time by using it properly).  But it hasn’t solved my problem completely.

    I already have panthenol and pentylene glycol in the formulation (cream for dry skin), but the former is sticky and the latter expensive.

    Glycerin just has a more comforting feel for my dry skin than the above mentioned materials. But at high concentration, it’s thick, has an initial tack until absorbed and has a funny smell (at least, the organic one I have from Alexmo has a slight, what people would describe as a “chemical” smell.. which I can’t remember if it was there in the non-organic glycerin I had previously from Alexmo).

    I am thinking of trying sorbitol next. @ngarayeva001, @Pharma, what do you like/dislike about sorbitol? And is powder or liquid preferable?

    I saw here that ethylhexylglycerin can mitigate some of the downsides of glycerin. Are there any other ingredients like this?

  • Pharma

    Member
    July 21, 2020 at 11:09 am
    IMHO sorbitol doesn’t last as long as glycerol but is less tacky. Can’t comment on the moisture performance.
    I prefer xylitol over sorbitol but for other reasons than humectancy.
    I usually work with dry/pure ingredients.
  • helenhelen

    Member
    July 21, 2020 at 12:20 pm

    Pharma said:

    IMHO sorbitol doesn’t last as long as glycerol but is less tacky. Can’t comment on the moisture performance.
    I prefer xylitol over sorbitol but for other reasons than humectancy.
    I usually work with dry/pure ingredients.

    @Pharma Thanks, that’s useful. How does sorbitol compare to betaine for you? Does it last longer?

  • Pharma

    Member
    July 21, 2020 at 3:37 pm
    Don’t know. Never ran them against each other.
    I like to play with combinations especially with betaine & polyols or urea. Can’t comment further because I’m still in the middle of playing :) .
  • ngarayeva001

    Member
    July 21, 2020 at 11:40 pm

    I couldn’t find many tables comparing hygroscopic properties of humectants, and unfortunately without it all our discussions is nothing but anecdotal evidence. I feel most of humectants are very similar. Sodium lactate is the least tacky, butylene and propylene glycol are the most versatile and compatible with other  materials,  (again just my own anecdotal perception), glycerin is cheap and effective for dry skin (not aesthetically pleasing but I tend to use it a lot) and urea is quite interesting, although I am still in the process of taming it. Betaine isn’t special in my opinion. Agree with Pharma, that mixing is the best approach. I always use several because they all perform optimally at different humidity.

  • hanbit

    Member
    July 23, 2020 at 12:56 pm

    @ngarayeva001I noticed that you’re a big fan of sodium lactate (saw you mentioned it several times in another thread). I tried adding 3% of sodium lactate to my emulsion, and it doesn’t smell great (sea salt + stale smell combined, I’m not great at describing smell though, but it is not a pleasant smell). The scent did go away after a minute or so but i’m wondering is there a way to mask of the scent without using any fragrances. What is your experiences though?

  • hanbit

    Member
    July 23, 2020 at 12:58 pm

    hanbit said:

    @ngarayeva001I noticed that you’re a big fan of sodium lactate (saw you mentioned it several times in another thread). I tried adding 3% of sodium lactate to my emulsion, and it doesn’t smell great (sea salt + stale smell combined, I’m not great at describing smell though, but it is not a pleasant smell). The scent did go away after a minute or so but i’m wondering is there a way to mask of the scent without using any fragrances. What is your experiences though?

    I did like the way it felt on my skin. And i tried it plain as well, and it definitely surpass glycerin and other glycols in terms of skin feel and moisture. It felt very hydrating without any tackiness (but smells awful)

  • emma1985

    Member
    July 23, 2020 at 3:51 pm

    hanbit said:

    hanbit said:

    @ngarayeva001I noticed that you’re a big fan of sodium lactate (saw you mentioned it several times in another thread). I tried adding 3% of sodium lactate to my emulsion, and it doesn’t smell great (sea salt + stale smell combined, I’m not great at describing smell though, but it is not a pleasant smell). The scent did go away after a minute or so but i’m wondering is there a way to mask of the scent without using any fragrances. What is your experiences though?

    I did like the way it felt on my skin. And i tried it plain as well, and it definitely surpass glycerin and other glycols in terms of skin feel and moisture. It felt very hydrating without any tackiness (but smells awful)

    Are you using powder Sodium Lactate or liquid?

  • ngarayeva001

    Member
    July 23, 2020 at 10:46 pm

    I use 60% liquid, but want to try powdered version too. I really like it but I also like carbomers and polymeric emulsifiers. Unfortunately these are not compatible with sodium lactate. If there’s one humectant that feels different (again as per my anecdotal experience) its sodium lactate. Re smell, it’s not that repulsive to me, so I kind of ignore it. Maybe I just got used to it, as it’s in the moisturizer I use everyday..

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