Home Cosmetic Science Talk Formulating Help my cleanser lather better - formula within

  • Help my cleanser lather better - formula within

    Posted by Zink on May 14, 2014 at 7:36 am

    Just wondering how I can thicken my cleanser formula below and get some more lathering action, right now it creates a too thick IMO lather, more like a gel that turns white: xanthan gum is possibly not the best thickener choice. Any ingredient ideas? Tweaks?

    Otherwise It’s a very nice, gentle, pH 4 formula that leaves your skin feeling clean and moist yet not totally stripped as with most soaps.

    Distilled Water
    Decyl Polyglucoside
    Sodium Cocoamphoacetate
    Lactic Acid
    Willow Bark Extract
    Sodium Lactate
    Vegetable Glycerin
    PEG-7 Glyceryl Cocoate
    Camellia Sinensis Leaf Extract
    Panthenol
    Allantoin
    Niacinamide
    Phenoxyethanol (and) Caprylyl Glycol (and) Sorbic Acid

    Zink replied 9 years, 12 months ago 4 Members · 12 Replies
  • 12 Replies
  • Chemist77

    Member
    May 14, 2014 at 7:50 am

    Try Crothix liquid from Croda, a very versatile thickener designed especially for such surfactant systems.

  • Zink

    Member
    May 14, 2014 at 8:37 am

    Will do I have it at hand, otherwise I’m using 0.5% Xanthan in the current formula.

  • Chemist77

    Member
    May 14, 2014 at 8:50 am

    This is specifically meant for such surfactant systems and I am sure it would perform much better than xanthan.

  • MakingSkincare

    Member
    May 14, 2014 at 9:23 am
    Niacinamide doesn’t do so well below pH5 (hydrolysis). 

    The glucosides don’t tend to thicken well with crothix, try HPMC instead. It takes a long time to hydrate though.

    Cocamidopropyl betaine is a good foam booster and the electrolytes in it can help with thickening too.
  • Chemist77

    Member
    May 14, 2014 at 9:32 am

    Since it seems to be a sulfate free formula I am confused if the electrolyte part of CAPB is really going to aid in thickening, though Zink you can try HPMC which might thicken better than Crothix. No harm in trying and letting us know as well.

    Cheers

  • Bobzchemist

    Member
    May 14, 2014 at 12:16 pm

    If you substitute Suganate 160 (APG Sulfonate) from Colonial for your Decyl polyglucoside, it will thicken synergistically with CAPB and salt.

    Also, glycerin is a foam suppressant - try using less.
  • Chemist77

    Member
    May 14, 2014 at 12:24 pm

    @Bobzchemist now thats a wow suggestion. Apologies but taking it further from here, I have formulated something similar with a little gold pearl. If I use Aculyn 22 its holding the pearl but without the presence of polymer gel network its settling down even if i am able to increase the viscosity. Do you think a gel network is must to keep these pearls sudpended??? Its a normal pearl like cloissone or timica gold pearl.
    Sorry again for encroaching!!!!!

  • Bobzchemist

    Member
    May 14, 2014 at 2:27 pm

    Suspension ability is a function of yield value/yield stress, not viscosity/thickness. It’s possible to formulate a relatively thin gel with good suspending capacity. 

  • Chemist77

    Member
    May 15, 2014 at 12:47 am

    @Bobzchemist wonderful explanation.

  • Zink

    Member
    May 15, 2014 at 4:24 am

    Thanks for reminding me about Niacinamide hydrolysis, had forgotten about that, the rate of hydrolysis at pH 4 is still low but better safe than sorry don’t want to trigger any flushing. http://onlinelibrary.wiley.com/doi/10.1002/jps.2600510710/abstract

    Will try HMPC.

    What humectants are considered good for cleansers? I read that glycerin stays on whereas sodium lactate/pca gets washed off. How about hyrwhatsitsname acid?

    Anything you guys feel is missing from this formula? I see that most cleanser use propylene glycol, presumable as a humectant and penetration enhancer?

  • Bobzchemist

    Member
    May 15, 2014 at 9:36 am

    Hey, @Perry, you want to help out here on types/thickness of foams?

    For humectants, I’d stick with glycerin. It’s cheap and it works. Why mess with that?
    Propylene Glycol, on the other hand, is used in most formulas as a carrier/solvent and sometimes a coupling agent. If you don’t need it, don’t put it in. (That statement should be carved over the door of every R&D lab)
  • Zink

    Member
    May 16, 2014 at 7:26 am

    So hyralonic acid is just hype? I guess it can still be used for gelling at low pH where you don’t want to use xanthan gum and carbomer won’t work well..

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