Home Cosmetic Science Talk Formulating Any thoughts about GMS o/w

  • Aziz

    Member
    February 21, 2021 at 9:53 am

    Is it an oil in water emulsifier?

  • Abdullah

    Member
    February 21, 2021 at 11:24 am

    @Aziz it was supposed to be Glyceryl stearate which is w/o. So what does this o/w mean here? 
    Is this the se (self emulsifying) version? 

  • Dr Catherine Pratt

    Member
    February 21, 2021 at 4:35 pm

    I thought it was just a general self emulsifier!!

  • Paprik

    Member
    February 21, 2021 at 6:11 pm

    Yeah, it should be Water in Oil. Meaning it’s primary emulsifier for water in oil emulsions (It has low HLB ~5.8), however it can be used as co-emulsifier for O/W emulsion or as a thickener. I don’t see any “SE”, that would indicate that it’s self-emulsifying. 

    A note, Glycerol Monostearate is the name, but its INCI name is Glyceryl Stearate. 

  • Abdullah

    Member
    February 22, 2021 at 2:24 am

    @”Dr Catherine Pratt” @Paprik 

    I made some samples from it to find out what it is. 

    First I made a sample with Stearamidopropyl Dimethylamine and it didn’t even make a lotion.
    SPDMA    %2
    This emulsifier  %3

    Second sample made a good looking cream and is completely stable since yesterday. No other thickner or stabilizer used.

    Petrolatum   %5
    Vegetable oil  %1
    This emulsifier  %6

    Does this mean it GMS se?

  • Microformulation

    Member
    February 22, 2021 at 4:20 pm
    What do they claim it is on the documentation? They should have at least listed a CAS #. That would tell you right away.
  • Aziz

    Member
    February 23, 2021 at 2:11 am

    Abdullah said:

    @Aziz it was supposed to be Glyceryl stearate which is w/o. So what does this o/w mean here? 
    Is this the se (self emulsifying) version? 

    The name of the self emulsifying version is , Glyceryl Stearate SE .
    Why it is mentioned here o/w ? 

  • Abdullah

    Member
    February 23, 2021 at 1:24 pm

    @Aziz that has confused me too. 
    It doesn’t have se

    Is has o/w written instead of w/o
    I have purchased it from a trader and he doesn’t know this technical parts of it. 
    I don’t think that it may be a printing mistake
  • Abdullah

    Member
    February 23, 2021 at 1:57 pm

    @Microformulation in most of  eastern countries they don’t do a lot of documentations for these small purchases especially if it is from a reseller. The cas no is not mentioned on it. I did email the seller after you mentioned it and am waiting for his answer if he knows. 

  • Microformulation

    Member
    February 23, 2021 at 6:03 pm

    Abdullah said:

    @Microformulation in most of  eastern countries they don’t do a lot of documentations for these small purchases especially if it is from a reseller. The cas no is not mentioned on it. I did email the seller after you mentioned it and am waiting for his answer if he knows. 

    Now you can see why we insist on these documents. It would be a simple issue.
    The HLB values are different.

    Glyceryl
    Stearate
    3.8
    Glyceryl Stearate SE 5.8
  • Pattsi

    Member
    February 24, 2021 at 5:15 am

    https://www.fineorganics.com/additives-for-cosmetics-and-pharma/finester-glyceryl-stearate

    They’re from India.
    They have different CAS from Glyceryl Stearate / Glyceryl Monostearate the one from Germany.

  • Abdullah

    Member
    February 24, 2021 at 1:39 pm

    @Microformulation they said the CAS # is 31566-31-1. 

    If the HLB of GMS se is 5.8, does it make o/w emulsion or w/o emulsion if used alone? 

  • Abdullah

    Member
    February 24, 2021 at 1:40 pm

    @Pattsi thanks a lot

  • Microformulation

    Member
    February 24, 2021 at 2:29 pm

    Abdullah said:

    @Microformulation they said the CAS # is 31566-31-1. 

    If the HLB of GMS se is 5.8, does it make o/w emulsion or w/o emulsion if used alone? 

    I wouldn’t use it alone. It needs a co-emulsifier. I doubt you could create a stable emulsion with it as a single emulsifier. Generally I see it predominately in O/W emulsions.

  • ngarayeva001

    Member
    February 24, 2021 at 9:18 pm

    I had a supplier who mislabeled GMS+PEG-100 stearate as ‘SE’. I bought smallest pack available and tested it in low ph formula. Since it emulsified I concluded it’s the version with PEG-100 and I ordered a larger pack. SE has soap and will turns emulsion into unpleasantly looking grainy ‘porrige’ under low ph. Testing SE vs just GMS like this doesn’t make too much sense though as GMS alone isn’t an emulsifier.

  • Abdullah

    Member
    February 25, 2021 at 1:45 am

    @Microformulation the some water was separated from cream on 3rd day.
    they also said the CAS # is 31566-31-1. So does it mean it is GMS?

  • Cafe33

    Member
    February 27, 2021 at 11:03 pm

    One CAS number, one distinct compound. 

  • AndrewSeel

    Member
    March 27, 2021 at 10:07 am

    GMS SE works fine in PH 5.5 when included in water phase O/W

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