Home Cosmetic Science Talk Formulating Does EDTA release the calcium it chelated from hard water back, if we reduce the pH to 4?

  • Does EDTA release the calcium it chelated from hard water back, if we reduce the pH to 4?

    Posted by Abdullah on November 19, 2021 at 4:23 am

    EDTA doesn’t chelate calcium at pH 4 correct?

    If we add 0.1% tetrasodium EDTA to hard water, the pH would be around 10 and it chelates all calcium. If we then reduce the pH to 4, will it releases the calcium that it had chelated back to water?

    The same question for magnesium. 

    Abdullah replied 3 years, 1 month ago 2 Members · 2 Replies
  • 2 Replies
  • ketchito

    Member
    November 19, 2021 at 2:39 pm

    @Abdullah Generally speaking, above a pH of 10, you’ll have EDTA with 4 carboxylic groups available to form the complex with metallic ions, while at a pH of 4, you’ll have only 2 (still being able to form a stable complex with divalent ions, but less with ions of higher oxidation state). 

  • Abdullah

    Member
    November 20, 2021 at 9:29 pm

    ketchito said:

    @Abdullah Generally speaking, above a pH of 10, you’ll have EDTA with 4 carboxylic groups available to form the complex with metallic ions, while at a pH of 4, you’ll have only 2 (still being able to form a stable complex with divalent ions, but less with ions of higher oxidation state). 

    Thanks

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