Home Cosmetic Science Talk Formulating Benzyl Alcohol and Dehydroacetic Acid

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  • Benzyl Alcohol and Dehydroacetic Acid

    Posted by chemnc on April 6, 2017 at 11:29 am

    Who has experience formulating with this preservative? I notice that it’s being used on many products to replace phenoxyethanol. I like that pH range is broad.

    eladmaayam replied 5 years, 9 months ago 6 Members · 10 Replies
  • 10 Replies
  • MarkBroussard

    Member
    April 6, 2017 at 12:09 pm

    It’s a good preservative, but a bit weak on mold … beef it up by adding some Sodium Benzoate at 0.4% to 0.5% … so your preservative actually becomes:

    Benzyl Alcohol, Sodium Benzoate, Dehydroacetic Acid.

  • chemnc

    Member
    April 6, 2017 at 12:54 pm

    I thought that with sodium benzoate you have to formulate at a very low pH. 

  • DRBOB@VERDIENT.BIZ

    Member
    April 6, 2017 at 2:18 pm

    With Na benzoate as per Chemac you have to be at PH 4-5 but have passed USP 51 with either BA or DHA alone.BA works well even at PH 9-used in OTC Antacids-

  • belassi

    Member
    April 6, 2017 at 9:44 pm

    DHA threw one of my ingredients out of solution and made a precipitate. Take care if you want to use it with salts.

  • MarkBroussard

    Member
    April 7, 2017 at 1:02 am

    What is the pH of your final formulation?  BA-DHA is good up to pH 7.0, but I would not use it alone at a pH above 6.0.  I always beef it up with additional fungicide.  The product is mostly BA (87%) and about 8% DHA … balance is water.

  • chemnc

    Member
    April 7, 2017 at 1:27 pm

    I’m staying under 6. The question is what fungicide to supplement it with. From what I’ve seen sodium benzoate has minimal activity at this pH.

  • DRBOB@VERDIENT.BIZ

    Member
    April 7, 2017 at 9:21 pm

    You may try sodium salt of DHA-Lonza

  • Berfot

    Member
    February 27, 2019 at 12:13 am

    Does anyone know where to buy small (ie, 4-8 oz) quantities of DHA + Benzyl Alcohol stateside? I’ve only found suppliers in the UK.

  • Berfot

    Member
    February 27, 2019 at 12:24 am

    Strike that, Making Cosmetics carries it.

  • eladmaayam

    Member
    February 27, 2019 at 7:23 pm

    From my experience BA has a tendency to yellowish when exposed to oxigen.
    I suggest adding antioxidant such as Vit-E at 0.2% if color is important

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