Home Cosmetic Science Talk Formulating hand wash formula

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  • hand wash formula

    Posted by nabil on December 29, 2016 at 6:31 pm

    hi all,

    i have a hand soap formula that i would like to confirm  if all parameters are ok:

    sls                                   6.4%
    cocamidopropyl betaine     2.9%.
    glycerin                              0.7%.
    sodium chloride                  0.55%.
    cocamide monoethanolamide   0.43%.
    fragrance                               0.5%.
    color                                     qs
    kython  cg                          0.150%.
    water                                     qs

    thank you in advance

    johnb replied 7 years, 11 months ago 7 Members · 25 Replies
  • 25 Replies
  • Bobzchemist

    Member
    December 29, 2016 at 6:55 pm

    Make some and find out. Kathon is a bit high, though. 0.10% is preferred.

  • nabil

    Member
    December 29, 2016 at 6:58 pm

    thx bob for the comment.
    i have seen that some hand sopas in market have YOGURT in their formula.
    any idea about such RM?

  • belassi

    Member
    December 29, 2016 at 8:24 pm

    Tiny amount of surfactants…

  • Bobzchemist

    Member
    December 29, 2016 at 8:48 pm

    Stay far, far away from yogurt in personal care. Belassi makes a good point - Surfactants need to be 5-10x higher.

  • nabil

    Member
    December 29, 2016 at 8:53 pm

    what is the issue with yogurt ?
    is there any heath concern?

  • belassi

    Member
    December 30, 2016 at 2:36 am

    what is the issue with yogurt ?
    is there any heath concern?
    well, not as long as you stay awake.
    if you fall asleep, your head will be eaten by ants.

  • belassi

    Member
    December 30, 2016 at 2:42 am

    actually I think that even with the proportions correctly adjust to say 20% minimum surfactant, this formulation will prove too harsh in the medium term. I would use SLES not SLS, the foam is better anyway, and I’d increase the amount of betaine. The cocamide MEA is fine and will give some foam stability and refattening effect. You might up that to 1%, not more as it will precipitate.

  • nabil

    Member
    December 30, 2016 at 11:38 am

    Thank you
    belassi for funny comment 🙂 

    here is one a good example of hand soap with yogurt.

    http://www.milmil.com/en/products/83/liquid-soap-yogurt-peach.html

    actually is a good product witch I want to develop something more similar.

     


  • johnb

    Member
    December 30, 2016 at 1:06 pm

    I very much doubt that yogurt is present in any useful amount and is there for marketing purposes only.

    Your formulation differs widely from the product shown in your link:

    • AQUA
      SODIUM LAURETH SULFATE
      SODIUM CHLORIDE
      COCAMIDE DEA
      COCAMIDOPROPYL BETAINE
      GLYCERIN
      PARFUM
      YOGURT
      COCO-GLUCOSIDE
      PROPYLENE GLYCOL
      TRIETHYLENE GLYCOL
      TETRASODIUM EDTA
      CITRIC ACID
      STYRENEACRYLATES COPOLYMER
      MAGNESIUM NITRATE*
      MAGNESIUM CHLORIDE*
      DMDM HYDANTOIN
      BENZYL ALCOHOL
      METHYLCHLOROISOTHIAZOLINONE*
      METHYLISOTHIAZOLINONE*
      CI 19140
      CI 14720

    I would definitely replace the Kathon CG (each of the items in the list which I have starred). I would also avoid DMDM Hydantoin (formaldehyde releaser).

  • MarkBroussard

    Member
    December 30, 2016 at 1:11 pm

    You can purchase Yogurt Extract from http://www.formulatorsampleshop.com … use 2% to 3% would be fine.  

  • Chemist77

    Member
    December 30, 2016 at 1:11 pm

    Kathon CG is recommended 0.1% maximum so stick to that. You can buy yogurt but to eat and use surfactants in the formula as suggested by others here. 

  • nabil

    Member
    December 30, 2016 at 1:31 pm

    my formula might be a starting formula that can modified to approach the Milmil product if possible.

    DMDM HYDANTOIN will not be used.
    i am wondering also about STYRENEACRYLATES COPOLYMER!
    is it use full in hand wash product?

  • johnb

    Member
    December 30, 2016 at 1:34 pm

    Used as an opacifier.

  • Chemist77

    Member
    December 30, 2016 at 1:41 pm

    Opulyn 301, will give you good opacity. Buttermilk is what you will have instead of yogurt

  • nabil

    Member
    December 30, 2016 at 2:00 pm

    i will add TETRASODIUM EDTA about 0.1%

  • nabil

    Member
    December 30, 2016 at 3:04 pm

    can we add COCO-GLUCOSIDE to formula above?

  • chickenskin

    Member
    December 30, 2016 at 5:49 pm

    @nabil

    yes you can use Coco-Glucoside
    its non-ionic.  i like this better…..

    pure HOH                                86.3%
    sls                                            8%
    cocamidopropyl betaine            3%
    Coco-Glucoside                        1%
    glycerin                                     1%
    EDTA                                        0.1%
    fragrance                                 0.5%.
    kathon  cg                                0.1%.
    NaCl                                           qs
    Citric Acid                                  qs

    pH ~6.5

    took out the coco MEA to cut heating cost.  you can add it back in.  due to low surfactant level you might get around 2000cps tops?  but it’ll work, and this is cheap!

  • johnb

    Member
    December 31, 2016 at 7:47 am

    chickenskin

    SLS has already been dicussed as a non-desirable ingredient.

    I continue to be uneasy about using Kathon CG. There are numerous antimicrobial presevatives available and I cannot understand why anyone should voluntarily use a substance which is a known contact allergen in any product.

  • nabil

    Member
    December 31, 2016 at 2:07 pm

    thank you very much chickenskin
    that make things easier for me.

    but i think i can replace sls by sles as per recommendation of some experts.
    i will forget either about adding yogurt or buttermilk.

    jhonb , can you please advice about another preservative that would suitable for such product?

  • johnb

    Member
    December 31, 2016 at 2:48 pm

    Gluconodeltalactone and Sodium Benzoate is accepted by ECOCERT as a preservative in certified organic cosmetics.

    A natural preservative that is a combination of a naturally occurring
    food additive glucono delta lactone, derived from corn, and a food
    grade preservative sodium benzoate, the sodium salt of benzoic acid,
    along with a trace amount of calcium gluconate as a processing agent.

    We recommend that you optimize (determine through interval testing
    the lowest effective dose) your preservative levels because all of the
    successful trials were done at use levels between 1.0% and 1.5%.

    The above is from http://www.ingredientstodiefor.com/item/Gluconolactone_Sodium_Benzoate_GSB_/565

    There are other commercial sources for this mixture.

    It is a suggestion only . I have not tested it myself but it does remove some of the question marks over thiazalone preservatives.

  • nabil

    Member
    January 3, 2017 at 11:08 pm

    is it possible to add sodium benzoate only as preservative?

  • johnb

    Member
    January 4, 2017 at 8:48 am

    Yes but as with all new formulae, it will need testing for antimicrobial efficiency - and other things such as chemical and physical stability.

    A mix I used to use as a general purpose preservative was a mix of benzoic acid and phenoxyethanol.

  • belassi

    Member
    January 4, 2017 at 5:23 pm

    I’ve been using sodium benzoate at 0.4% as a preservative for shampoos for years. Zero problems.

  • nabil

    Member
    January 11, 2017 at 7:13 pm

    here is an example that show sodium benzoate as preservative.
    http://www.beaute-test.com/sanex_zero_0__sanex.php

    sanex shampoo ZERO

  • johnb

    Member
    January 12, 2017 at 7:51 am

    The Sanex product also contains lactic acid so the active preservative may be benzoic acid.

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