Home Cosmetic Science Talk Formulating Advanced Questions SHAMPOO HAS BEEN SEPERATED

  • SHAMPOO HAS BEEN SEPERATED

    Posted by cosmetic_chemist_vietnam on August 27, 2024 at 3:01 am

    Hello everyone, I need your help. We are doing a sulfate-free shampoo, using AOS, CAB as primary and secondary surfactant relatively and using guar gum and PEG-120 methyl glucose dioleate as thickeners. After a few weeks storage, we have a problem that guar gum has been seperated (lower layer). Can anyone explain why and how can we solve this problem?

    cosmetic_chemist_vietnam replied 2 weeks, 4 days ago 3 Members · 4 Replies
  • 4 Replies
  • evchem2

    Member
    August 27, 2024 at 11:00 am

    Do you know how much salt is in your formulation ( for example, CAPB normally has ~5% salt content when sold as ~30% ASM)? What is your ASM (active surfactant matter) overall?

    You can google “phase separation salt polymer systems” or “aqueous two phase system” to see that when enough of both polymer and salt are present in a system, it will separate into two phases- one rich with polymer and the other rich with salt.

    • cosmetic_chemist_vietnam

      Member
      August 29, 2024 at 4:52 am

      <font style=”vertical-align: inherit;”><font style=”vertical-align: inherit;”>Thnank you, I appreciate that :D</font></font>

  • ketchito

    Member
    August 28, 2024 at 9:33 am

    Can you make a sample without PEG-120 methyl glucose dioleate? In some systems, it tends to gel the product. What you see at the bottom might be water, and the upper part might be a surfactant-rich phase.

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